ARTIFICIAL ICE
The production of cold by artificial means began at a much earlier
date than is commonly supposed. In India, Arabia, China,, Egypt, and
other eastern countries, porous earthen vessels were used for
keeping water cool by the agency of evaporation from the surface of
the vessels; and it has already been told on a preceding page how
the same idea was applied in very ancient times for the production
of ice itself. Wine bottles were kept cool by wrapping them in wet
cloths, handsomely ornamented when the bottles were in actual use on
the table. After snow and ice came into popularity a simple cooling
mixture was made by adding salt to those substances. The salt
hastened their melting and extracted the heat of the bodies to be
cooled more rapidly than either snow or ice would do it alone. Ether
was also known at a very early date to produce cold by evaporation.
In India, owing to the cheapness of niter, it has been common to use
a solution of niter and water as a cooling mixture for wine. The
record of definite attempts to produce freezing mixtures in a
scientific manner begins with the Italians in the sixteenth century.
Lord Bacon took much interest in the experiments made in his time;
and in 1795, as a result of the studies of b1i•. Walker, of Oxford,
England, a number of tables of freezing mixtures were printed in the
Philosophical Transactions of that year. Professor Leslie, of
England, produced a considerable degree of refrigeration on the
principle of exposing in the exhausted receiver of an air-pump
sulfuric acid, a substance rapidly absorbing vapor. The problem of
freezing by artificial means interested a great many minds at the
same time, both iu England and on the continent. Among other plans
tried was the purely mechanical one of placing a quantity of water
in the receiver of an air-pump and exhausting the air by powerful
machinery, the slow evaporation of the water producing cold intense
enough for the purpose. In 1834 an American in London, Jacob
Perkins, patented a machine for ice-making, by the evaporation of
sulfuric ether under an air-pump. The machine was afterwards
improved by Professor Twining, of New Haven (1S50); Harrison, of
Australia (1857); Siebe, of London (1562); and later by Siddeley and
Mackay, of Liverpool and London. When attention had been briefly
turned to the use of' volatile substances other liquids than ether
wire sought for; and during the last forty years a great many
experiments have been made with a wide range of substances. The
French have been especially active and ingenious in this field of
research, and the name of their leading inventor, Carr6, is now
indissolubly connected with the successful application of the idea
of evaporating a volatile fluid for the making of excellent and
inexpensive ice. Among the new experiments made were those with
ammonia, metylic ether, sulfurous acid, bisulfide of carbon,
naphtha, and gasoline, or chimogene. Incidentally during the study
of this subject some remarkable results were obtained. By the
evaporation of sulfurous acid the temperature of 1000 Fahrenheit
below zero has been produced, and carbonic acid gas converted into a
liquid, by the evaporation of which, in turn, the so-called
permanent gases have been converted, under pressure, into liquids.
Time and experiment have eliminated many of the substances above
referred to from use; and the practical ice-machines of the present
day employ only ammonia, ether, or sulfurous acid.
There are now about forty different styles of ice-machines in operation
in different parts of the world, Nearly a hundred have been patented at
Washington. Not over half a dozen, however, are in this country
considered of much practical value at the present time. The machines are
all the same in principle, though various in construction. The principle
is that a liquid in changing its form to a vapor abstracts beat from all
surrounding substances; the more rapid the evaporation the more intense
being the cold produced. The chief troubles the inventors have
encountered have been the danger of explosion, to which the ether
machine is especially liable; the leakage of the gases through the
joints and pumps, which, by diminishing the pressure within, destroys
the efficiency of the machine; the fact that an invention which will
work successfully in a northern climate sometimes proves a failure in a
warmer region, and the frequent great cost of operation. In order to
carry on a successful business in artificial ice-making the product must
be manufactured at a cost of not to exceed $2 or $3 a ton. The chief
cause of the numerous disastrous failures so far has been that the
product cost anywhere from $20 to $250 a ton. One American proprietor
lost $100,000 in experiments at New Orleans before success was achieved.
It has been the aim of inventors in this country to make ice at from 75
cents to $1 per ton. Many times during the last ten years the
announcement has been made that the result has been accomplished. It is
doubtful if, in practice, any ice-maker in America has yet been able to
produce ice so cheaply; but the cost has, nevertheless, been reduced at
length to a point where the making of ice is commercially practicable,
and it is now carried on as a regular industry in a large number of
southern cities in competition with the importation of natural ice from
the north.
The process of ice-making is substantially the same in all machines, and
a description of the way the thing is done by the Louisiana Ice
Manufacturing Company of New Orleans will give a correct notion of it.
The substance employed for evaporation is ammonia. In its uncombined
form ammonia is a gas, having a remarkable affinity for wafer. A
compound of water and ammonia is placed in an iron retort, or boiler,
the fluid being deep enough to cover a coil of pipe in the bottom of the
retort, occupying about one-third of its capacity. A current of steam is
sent through this coil to heat the water to from 1300 to 1500, and to
volatilize the ammonia. The heat disengages the gas, which rises into
the top of the retort, and is carried off into a series of pipes in a
square box, called the “liquidator." Cold water circulates in a constant
current around the pipes of the liquidator, and the gas condenses to a
liquid under the influences of the refrigeration it receives and the
pressure of the new gas which is continually coming. The liquid ammonia
flows into a reservoir below called the "recipient" until a sufficient
quantity has accumulated to begin the work of making ice. It is the
return of this liquid to its gaseous form, or, in other words, its
evaporation when pressure is removed, that generates the ice. A stopcock
is opened which allows the ammonia to flow from the recipient into and
through a network of pipes which fill the interior of a large tank
called the "refrigerator." Finding room for expansion, the ammonia
rushes into the pipes, vaporizes, absorbs heat in the process from the
salt water surrounding the pipes, and rapidly reduces the temperature of
the brine much below the freezing point. The brine, thus suddenly
cooled, in turn absorbs beat from shallow pans of fresh water which are
suspended in the refrigerator, and the fresh water is converted into
blocks of solid ice. If this were the end of the process ice-making
would be too expensive for commercial success. But so far only one-half
of the business of the machine has been performed. The next step is to
recover the gaseous ammonia for use it second time. When the ammonia was
volatilized in the retort by heat a great pressure was generated. The
water was forced back out of the bottom of the retort through a tube
into an exchange or drum near by, and thence into it cooler, and still
on into a "vase of absorption." Here the cooled water meets the gaseous
ammonia, which has gone on through the refrigerator and has been
conducted through tubes to the vase of absorption. The ammonia combines
by affinity with the water again, forming a new saturated solution, and
this is pumped back into the retort to undergo another operation. The
gas, is thus, used over and over again. It is this part of the process
which secures the economy of ice-making. This machine will make an
average of 18 to 19 tons of ice a day, or about 5,500 tons a year.
Another variety of ammonia machine is used by the New Orleans Ice
Manufacturing Company. It is the California invention of Mr. Beath. The
principle is in all respects the same, but the ice is made not by
freezing it in pans, but allowing it to form on the pipes of the
refrigerating tank. The pipes are vertical, 32 feet high, placed in rows
4 feet apart one way, and 2 feet apart the other. When the liquid
ammonia is allowed to enter them and evaporate into gas, water is
showered upon the pipes and the ice forms on their surface, growing
continually in thickness as long as evaporation continues. Water is
thrown upon the pipes greatly in excess of the quantity that can be
frozen. The result is that any solid substances contained in the water
are washed down by the current, and thus the muddy water of the
Mississippi river yields a pure and brilliant ice. The columns of ice
around the pipes grow in diameter until they meet. They finally become
transformed into perpendicular walls of solid ice, 32 feet high, and
about 3 feet thick. Freezing is then stopped; gaseous ammonia is forced
back into the pipes under pressure. Under compression heat is given out
and the ice is melted away from immediate contact with the pipes.
Horizontal and vertical grooves are then cut in the walls of ice and the
blocks are split out and carried away for consumption. The house of the
New Orleans company is large enough to hold 10,000 tons of ice. It is
divided into four compartments, in which the vertical iron pipes are
erected. In the winter of 7882-'83, with only half its apparatus hi use,
the product was 50 tons a day.
Other machines have been tried in America, in which sulfurous acid and
other liquids have been volatilized by creating a vacuum with a powerful
pump, the liquid afterward being condensed under pressure. Two of the
Roach line of steamers to Brazil were supplied with refrigerating
apparatus of this class. The work done did not yield satisfactory
results, and the machines were taken out. Inventions of this class are
being used, however, in various parts of the United States.
Within a few years a class of machines has been brought out, intended
not for the manufacture of ice, but for the refrigeration of storage
rooms by cooling the air. They are ammonia machines, as a rule, and in
large establishments have been found to give satisfaction. They have
been introduced to breweries in large numbers within the last five
years. There are those who now predict their universal adoption by
brewers within the -next ten years, at least by all the large firms. It
will be cheaper for the smaller firms to buy natural ice. A year of
short supply and high prices tends to increase greatly the number of
machines iii the breweries of the large firms.
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